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	<title>DP Chemistry: Reactions of organic compounds</title>
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href="../19287/proteins-enzymes--1.html">Proteins & enzymes </a></li><li><a href="../19291/lipids-1.html">Lipids</a></li><li><a href="../19299/carbohydrates--1.html">Carbohydrates </a></li><li><a href="../19305/vitamins--1.html">Vitamins   </a></li><li><a href="../19313/biochemistry-the-environment--1.html">Biochemistry & the environment </a></li><li><a href="../19336/proteins-enzymes-ahl--1.html">Proteins & enzymes (AHL)   </a></li><li><a href="../19347/nucleic-acids--1.html">Nucleic acids   </a></li><li><a href="../19361/biological-pigments--1.html">Biological pigments   </a></li><li><a href="../19366/stereochemistry-in-biomolecules-1.html">Stereochemistry in biomolecules</a></li></ul></li><li><a href="../19390/option-c--1.html" class="father">Option C </a><ul class="level-2"><li><a href="../19391/energy-sources-1.html">Energy sources</a></li><li><a href="../19407/fossil-fuels-1.html">Fossil fuels</a></li><li><a href="../19411/nuclear-fusion-nuclear-fission-reactions-1.html">Nuclear fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL)    </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin  </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li><a href="../19211/environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine  </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li class="selected"><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">&#039;Scaffolding&#039; the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li class="selected"><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier&#039;s principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li class="selected"><a href="reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../18852/data-logging--1.html">Data logging </a></li><li><a href="../18853/software-for-graph-plotting--1.html">Software for graph plotting </a></li><li><a href="../18854/spreadsheets-for-data-processing--1.html">Spreadsheets for data processing </a></li><li><a href="../18855/databases-1.html">Databases</a></li><li><a href="../18856/computer-modelling-simulations--1.html">Computer modelling & simulations </a></li></ul></li><li><a href="../16594/group-4-project-1.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../16595/practicalities-1.html">Practicalities</a></li><li><a href="../16596/reflective-statement--2.html">Reflective statement </a></li></ul></li><li><a href="../16666/a-new-laboratory-1.html">A new laboratory?</a></li></ul></li><li><a href="../16284/exams-1.html">Exams</a><ul class="level-1"><li><a href="../16286/essential-facts-1.html" class="father">Essential Facts</a><ul class="level-2"><li><a href="../16287/objectives-command-terms-1.html">Objectives & command terms</a></li><li><a href="../16288/grade-descriptors-1.html">Grade descriptors</a></li><li><a href="../16289/grade-boundaries-1.html">Grade boundaries</a></li></ul></li><li><a href="../16302/paper-1-multiple-choice-1.html" class="father">Paper 1 (Multiple Choice)</a><ul class="level-2"><li><a href="../16303/advice-to-students-paper-1-1.html">Advice to students (Paper 1)</a></li><li><a href="../31515/practice-paper-1-exams-1.html">Practice Paper 1 exams</a></li></ul></li><li><a href="../16305/paper-2-1.html" class="father">Paper 2</a><ul class="level-2"><li><a href="../16306/advice-to-students-paper-2-1.html">Advice to students (Paper 2)</a></li><li><a href="../16307/areas-of-difficulty-1.html">Areas of difficulty</a></li></ul></li><li><a href="../16313/paper-3--1.html" class="father">Paper 3 </a><ul class="level-2"><li><a href="../16314/advice-to-students-paper-3-1.html">Advice to students (Paper 3)</a></li><li><a href="../16342/data-response-questions-1.html">Data response questions</a></li><li><a href="../20054/experimental-work-questions-1.html">Experimental work questions</a></li></ul></li><li><a href="../16324/the-examination-process-1.html" class="father">The examination process</a><ul class="level-2"><li><a href="../16316/setting-the-exam-papers-1.html">Setting the exam papers</a></li><li><a href="../16317/predicted-grades-1.html">Predicted grades</a></li><li><a href="../16318/marking-the-papers-1.html">Marking the papers</a></li><li><a href="../16319/commenting-on-the-exams-1.html">Commenting on the exams</a></li><li><a href="../16320/grade-awarding-1.html">Grade Awarding</a></li><li><a href="../16321/enquiry-upon-results-1.html">Enquiry upon results</a></li><li><a href="../16322/chief-examiners-report-1.html">Chief Examiner&#039;s report</a></li><li><a href="../16323/retaking-the-exam-1.html">Retaking the exam</a></li></ul></li><li><a href="../16325/faqs-1.html">FAQs</a></li></ul></li><li><a href="../3147/ib-core-1.html">IB Core</a><ul class="level-1"><li><a href="../3149/learner-profile-1.html">Learner Profile</a></li><li><a href="../21735/extended-essays--1.html" class="father">Extended Essays </a><ul class="level-2"><li><a href="../21736/overview--1.html">Overview </a></li><li><a href="../21780/responsibilities-1.html">Responsibilities</a></li><li><a href="../21790/resources-1.html">Resources</a></li><li><a href="../21800/research-1.html">Research</a></li><li><a href="../21804/writing-the-essay-1.html">Writing the essay</a></li><li><a href="../21810/assessment-1.html">Assessment</a></li><li><a href="../22434/summary-of-advice--1.html">Summary of advice </a></li><li><a href="../25272/faqs--1.html">FAQs </a></li></ul></li><li><a href="../307/theory-of-knowledge-tok-1.html" class="father">Theory of Knowledge (TOK)</a><ul class="level-2"><li><a href="../41171/the-12-tok-concepts-1.html">The 12 TOK concepts</a></li><li><a href="../3507/why-tok-chemistry-1.html">Why TOK & Chemistry?</a></li><li><a href="../3505/a-modern-paradigm-1.html">A modern paradigm</a></li></ul></li></ul></li><li><a href="../17783/fast-track-to-tests-questions-1.html">Fast track to tests & questions</a><ul class="level-1"><li><a href="../17784/sl-multiple-choice-tests-on-individual-topics-1.html">SL Multiple choice tests on individual topics</a></li><li><a href="../24351/sl-multiple-choice-quizzes-on-sub-topics-1.html">SL Multiple choice &#039;quizzes&#039; on sub-topics</a></li><li><a href="../31519/sl-practice-paper-1-exams-1.html">SL Practice Paper 1 exams</a></li><li><a href="../17786/sl-questions-on-each-sub-topic-1.html">SL Questions on each sub-topic</a></li><li><a href="../20431/sl-paper-3-section-a-questions-1.html">SL Paper 3 Section A questions</a></li><li><a href="../17792/sl-questions-on-the-options-1.html">SL Questions on the options</a></li><li><a href="../24897/sl-quizzes-on-option-sub-topics--1.html">SL Quizzes on option sub-topics </a></li><li><a href="../17785/hl-multiple-choice-tests-on-individual-topics-1.html">HL Multiple choice tests on individual topics</a></li><li><a href="../24352/hl-multiple-choice-quizzes-on-sub-topics-1.html">HL Multiple choice &#039;quizzes&#039; on sub-topics</a></li><li><a href="../31520/hl-practice-paper-1-exams--1.html">HL Practice Paper 1 exams </a></li><li><a href="../17787/hl-questions-on-each-sub-topic--1.html">HL Questions on each sub-topic </a></li><li><a href="../20428/hl-paper-3-section-a-questions-1.html">HL Paper 3 Section A questions</a></li><li><a href="../17793/hl-questions-on-the-options-1.html">HL Questions on the options</a></li><li><a href="../24973/hl-quizzes-on-option-sub-topics-1.html">HL Quizzes on option sub-topics</a></li><li><a href="../41573/printable-versions-of-written-tasks--1.html">Printable versions of written tasks </a></li></ul></li><li><a href="../41465/complete-course-for-students--2.html">Complete course for students </a><ul class="level-1"><li><a href="../27988/full-coverage-of-each-topic-and-sub-topic-2.html" class="father">Full coverage of each topic and sub-topic</a><ul class="level-2"><li><a href="../27959/topic-1-stoichiometric-relationships-1.html">Topic 1 : Stoichiometric relationships</a></li><li><a href="../27960/topics-2-12-atomic-structure-1.html">Topics 2 & 12 : Atomic structure</a></li><li><a href="../27965/topics-3-13-periodicity-1.html">Topics 3 & 13 : Periodicity</a></li><li><a href="../27971/topics-4-14-chemical-bonding-structure-1.html">Topics 4 & 14 : Chemical bonding & structure</a></li><li><a href="../27987/topics-5-15-energeticsthermochemistry-1.html">Topics 5 & 15 : Energetics/thermochemistry</a></li><li><a href="../27995/topics-6-16-chemical-kinetics-1.html">Topics 6 & 16 : Chemical kinetics</a></li><li><a href="../28001/topics-7-17-equilibrium--1.html">Topics 7 & 17 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</div><section id="main-content"><div class="blueBg"><h1><img alt="" height="21" src="../../../img/tib-icons/standard-level-32-1.png" title="" width="21"> <img alt="" height="21" src="../../../img/tib-icons/higher-level-32-1.png" title="" width="21"> Background information and teacher&#39;s notes</h1><p>This is very much a practical introduction to organic chemistry and is excellent for demonstrating (or reinforcing) the underlying theory. The aim is to <span data-scayt-word="familiarise" data-wsc-lang="en_US">familiarise</span> students with some basic organic compounds and to get them to relate physical and chemical properties to particular functional groups. All of the functional groups are on the core in <a href="../18475/topics-10-20--1.html" title="New 2014 programme (First exams 2016) » Core &amp; AHL » Teaching each topic &amp; sub-topic » Topics 10 &amp; 20 ">Topic 10 : Organic chemistry</a>. The practical is also useful to help <span data-scayt-word="familiarise" data-wsc-lang="en_US">familiarise</span> students with the <span data-scayt-word="IUPAC" data-wsc-lang="en_US">IUPAC</span> way of naming organic compounds.</p><p>All the reactions are small-scale test-tube type reactions. You may need to substitute some chemicals if you do not have the precise ones in stock but provided they contain the same functional groups this should make little difference. It may be the first time that students have handled organic compounds in the laboratory. They should be made aware that most are very volatile and also very flammable. They should avoid breathing in <span data-scayt-word="vapours" data-wsc-lang="en_US">vapours</span> as much as possible and if they need to heat the compounds it should be done using a water bath and never with a naked flame.</p><p>Adding water in experiment <strong>1.</strong> simply demonstrates that the solubility of organic compounds in polar solvents such as water depends both on the polarity of the functional group and on the length of the carbon chain.</p><p>In terms of the chemistry it is worth reminding them about testing for <span data-scayt-word="unsaturation" data-wsc-lang="en_US">unsaturation</span> in experiment 2. Books just say add bromine water and observe if the bromine solution is <span data-scayt-word="decolourised" data-wsc-lang="en_US">decolourised</span>. They should <span data-scayt-word="realise" data-wsc-lang="en_US">realise</span> that they only need to add a small amount of bromine water i.e. the unsaturated compound should be in excess &ndash; sometimes students add far too much bromine water and are then surprised when it does not change <span data-scayt-word="colour" data-wsc-lang="en_US">colour</span>. The reaction between hydrocarbons and halogens in sunlight is also on the core part of the <span data-scayt-word="programme" data-wsc-lang="en_US">programme</span> under <a href="../18597/alkanes-alkenes-addition-polymers-1.html" title="Alkanes, alkenes &amp; addition polymers">10.2</a>. Students should <span data-scayt-word="realise" data-wsc-lang="en_US">realise</span> that saturated hydrocarbons can also <span data-scayt-word="decolourise" data-wsc-lang="en_US">decolourise</span> bromine water but the reaction is much slower and needs the presence of ultra-violet light. If it is a sunny day then it takes about five minutes in bright sunlight for the reaction to work. Iron filings act as a halogen carrier and speed up the reaction between <span data-scayt-word="methylbenzene" data-wsc-lang="en_US">methylbenzene</span> and bromine water. This could also be included if you wish but it is not required as an example of electrophilic substitution in 20.2. However it is much easier to do this practically than nitrate benzene, which is the example given.</p><p class="MsoNormal"><img alt="" class="left" height="314" src="../../../ib/chemistry/images/Practicals/Making esters.JPG" title="My students making esters - yes, I know they should have their safety glasses on!" width="235">Students need to know about weak acids and they should see that the solubility in water of organic acids such as benzoic acid increases dramatically when they are reacted with sodium hydroxide to form ionic salts. By deduction a similar effect is found when amines (which are weak bases) are reacted with acids to again form ionic salts. The chemistry of this is important for <a href="../19078/option-d-1.html" title="Options » Option D">Option D: Medicinal chemistry</a>. Many medicines (or illegal drugs) contain amine groups and are administered as their chloride salts - this is covered in more details in the page on <a href="../17377/salt-formation--1.html" title="New 2014 programme (First exams 2016) » Basic information » Resources » Novel uses for the IB data booklet » Salt formation ">salt formation </a> under <a href="../17348/novel-uses-for-the-ib-data-booklet--1.html" title="New 2014 programme (First exams 2016) » Basic information » Resources » Novel uses for the IB data booklet ">Novel uses for the IB data booklet</a>. There are also good examples that are discussed in several of my blog pages including <a href="chemistry/blog/3151/plant-food-or-drug">Plant food or drug</a><a href="http://chemistry/blog-post/3151/plant-food-or-drug.htm">?</a>, <a href="http://www.thinkib.net/chemistry/blog/7961/blue-light-cystoscopy">Blue light cystoscopy</a>, <a href="https://www.thinkib.net/chemistry/blog/27440/applying-ib-chemistry-to-a-diet-pill">Applying IB chemistry to a diet pill</a> and <a href="https://www.thinkib.net/chemistry/blog/19818/tamoxifen">Tamoxifen</a> as well as in a newspaper article on <a href="../17133/newspaper-articles-1.html" title="New 2014 programme (First exams 2016) » Basic information » Resources » Newspaper articles">Shop until you pop</a>.</p><p>The classification of alcohols into primary, secondary and tertiary and their response to mild oxidation is part of sub-topic 10.2. At SL students also need to be able to <span data-scayt-word="recognise" data-wsc-lang="en_US">recognise</span> the ester functional group and know the reaction between a carboxylic acid and an alcohol to make esters. It is fun for them to make an ester practically and smell the product (see right). After they have made ethyl <span data-scayt-word="ethanoate" data-wsc-lang="en_US">ethanoate</span> I get them to react a spatula full of salicylic acid (<span data-scayt-word="2-hydroxybenzoic" data-wsc-lang="en_US">2-hydroxybenzoic</span> acid) with a small amount of methanol in the same way (i.e. with a few drops of concentrated sulfuric acid acting as the catalyst). This will give them the very characteristic smell of methyl salicylate &ndash; which different cultures give different common names to. In the UK it is known as &#39;oil of wintergreen&#39; and many students will <span data-scayt-word="recognise" data-wsc-lang="en_US">recognise</span> it as the smell of <span data-scayt-word="germolene" data-wsc-lang="en_US">germolene</span> or liniment to treat muscular pains</p><p>When they have finished the practical I briefly explain the chemistry behind the reactions. Then as we cover the chemistry in more detail in class I can refer back to these reactions and where necessary get them to write mechanisms as well as overall equations.</p><hr class="hidden"></div><hr class="hidden"><div class="box"><h2><img alt="Standard Level" class="ico" src="../../../img/icons/standard-1.png" title="Standard Level"> <img alt="Higher Level" class="ico" src="../../../img/icons/higher-1.png" title="Higher Level"> Student worksheet</h2><hr class="hidden"><p style="text-align: center;"><strong>REACTIONS OF ORGANIC COMPOUNDS</strong></p><hr class="hidden"><p>The aim of this practical is to compare and contrast the chemical properties and reactivities of some simple organic molecules containing different functional groups.</p><hr class="hidden"><p><strong>ENVIRONMENTAL CARE: </strong></p><p>After you have carried out the following reactions place any residues remaining in the container in the fume cupboard marked &#39;Organic Waste&#39;. Do not pour organic waste down the sink.</p><hr class="hidden"><p><strong>SAFETY: </strong></p><p>Organic compounds tend to be highly inflammable. Keep them away from naked flames and keep the stoppers on the reagent bottles when not in use. Use only small quantities and use a water bath for heating. As much as possible avoid breathing in their fumes.</p><hr class="hidden"><p><strong>PROCEDURE:</strong></p><p><strong>1. Solubility.</strong> Generally only small polar molecules dissolve easily in water. Check this by adding a few drops of each of the following compounds to small quantities of cold water: cyclohexane, ethanol, <span data-scayt-word="butan-1-ol" data-wsc-lang="en_US">butan-1-ol</span>, <span data-scayt-word="octan-1-ol" data-wsc-lang="en_US">octan-1-ol</span>, <span data-scayt-word="propanone" data-wsc-lang="en_US">propanone</span> and cyclohexanone</p><p><strong>2. Reactivity of the hydrocarbons</strong>. Add a few drops of bromine solution to a few drops of each of the three hydrocarbons, cyclohexane, <span data-scayt-word="cyclohexene" data-wsc-lang="en_US">cyclohexene</span> and <span data-scayt-word="methylbenzene" data-wsc-lang="en_US">methylbenzene</span> (used instead of benzene) in small test-tubes. In the case of cyclohexane compare the effects of exposure to sunlight by placing one tube near the window and, to total darkness, by placing a second tube in the cupboard for the same length of time.</p><p><strong>3. Acidity and basicity</strong>. Most organic compounds are neutral in their response to a pH test. The following compounds are different.</p><p><strong>(a) </strong>Half fill four micro test tubes with distilled water. To the first add 4 drops of <span data-scayt-word="ethylamine" data-wsc-lang="en_US">ethylamine</span> solution, to the second 4 drops of phenylamine, to the third 4 drops of <span data-scayt-word="ethanoic" data-wsc-lang="en_US">ethanoic</span> acid and to the fourth a small amount of benzoic acid. Add 4 drops of universal indicator to each tube, mix and determine the pH by the <span data-scayt-word="colour" data-wsc-lang="en_US">colour</span> of the solution formed.</p><p><strong>(b)</strong> To 4 drops of phenylamine, add 10 drops of distilled water. Does it dissolve? Now add 5 or more drops of dilute hydrochloric acid and observe whether there is any tendency to dissolve.</p><p><strong>(c)</strong> To a small amount of benzoic acid, add 10 drops of distilled water. Does it dissolve? Now add 5 or more drops of dilute sodium hydroxide solution and observe what happens.</p><p><strong>4. Two reactions of ethanol</strong>.</p><p><strong>(a)</strong> <strong>Oxidation</strong>. Mix 10 drops of potassium dichromate(VI) solution with 10 drops of dilute sulfuric acid. Add 4 drops of this mixture to 5 drops of ethanol in a micro test tube and warm in a beaker of hot water. Observe any changes in <span data-scayt-word="colour" data-wsc-lang="en_US">colour</span> and smell.</p><p><strong>(b) Esterification</strong>. Mix 10 drops of ethanol with 10 drops of &#39;glacial&#39; <span data-scayt-word="ethanoic" data-wsc-lang="en_US">ethanoic</span> acid and add 2 drops of concentrated sulfuric acid (care!). Warm the mixture in hot water for 5 minutes, then pour into 25 cm<sup>3</sup><sup> </sup>of dilute sodium carbonate solution. This removes the smell of any <span data-scayt-word="unreacted" data-wsc-lang="en_US">unreacted</span> <span data-scayt-word="ethanoic" data-wsc-lang="en_US">ethanoic</span> acid. Smell the product carefully and try to describe it.</p><hr class="hidden"><p><strong>QUESTIONS</strong></p><p><strong>1. </strong>Try to explain your observations giving relevant equations for any reactions taking place.</p><p><strong>2.</strong> Look up benzene on the chemistry HAZARD cards. Why was <span data-scayt-word="methylbenzene" data-wsc-lang="en_US">methylbenzene</span> used instead of benzene in experiment <strong>2</strong>? If benzene had been used how would you have expected it to react?</p><hr class="hidden"></div><hr class="hidden"><p>This worksheet can also be downloaded from:</p><p><a href="/media/ib/chemistry/files/2014%20practicals/Reactions-of-organic-compounds.pdf" target="_blank" title="Worksheets"><img class="ico" src="../../../img/icons/exercise-1.png">&nbsp;<img alt="" height="16" src="../../../img/tib-icons/standard-level-24-1.png" title="" width="16"> <img alt="" height="16" src="../../../img/tib-icons/higher-level-24-1.png" title="" width="16"> Reactions of organic compounds</a></p></section></article><section id="media-extras"><div class="page-actions no-print navbar inline hidden-desktop"><div class="navbar-inner"><ul class="nav"><li><a class="presentation" href="#" onclick="return false;"><i class="fa fa-desktop"></i></a></li><li><a class="print-section-blog" href="#" onclick="return false;"><i class="fa fa-print"></i></a></li><li><a class="page-bookmarker" data-ticket="IB Docs (2) Team" data-pid="18598" href="#" onclick="return false;"><i class="fa fa-star"></i></a></li><li><a class="personal-notes" href="#" onclick="return false;"><i class="fa fa-file-text"></i></a></li><li><a class="" data-toggle="modal" href="#modal-feedback" onclick="return false;"><i class="fa fa-envelope-o"></i></a></li><li class="dropdown"><a class="dropdown-toggle" data-toggle="dropdown" data-target="#" href="#"><i class="fa fa-share-alt"></i></a><ul class="dropdown-menu" role="menu"><li><a class="" target="_blank" title="Share on Twitter" href="https://twitter.com/share?text=%22Reactions+of+organic+compounds%22+-+via+%40InThinker+%23chemistry%0A&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18598%2Freactions-of-organic-compounds"><i class="fa fa-twitter-square"></i><span>Twitter</span></a></li><li><a class="" target="_blank" title="Share on Facebook" href="https://www.facebook.com/sharer.php?u=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18598%2Freactions-of-organic-compounds&t=Reactions+of+organic+compounds"><i class="fa fa-facebook-square"></i><span>Facebook</span></a></li><li><a class="" href="http://www.linkedin.com/shareArticle?mini=true&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18598%2Freactions-of-organic-compounds"><i class="fa fa-linkedin-square"></i><span>LinkedIn</span></a></li><li><a class="" href="https://plus.google.com/share?url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F18598%2Freactions-of-organic-compounds"><i class="fa fa-google-plus-square"></i><span>Google +</span></a></li><li><a class="" href="mailto:?subject=Reactions of organic compounds&body=This is very much a practical introduction to organic chemistry and is excellent for demonstrating (or reinforcing) the underlying theory. 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