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<title>DP Chemistry: Environmental impact of some medications</title>
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</a></li><li><a href="../19287/proteins-enzymes--1.html">Proteins & enzymes </a></li><li><a href="../19291/lipids-1.html">Lipids</a></li><li><a href="../19299/carbohydrates--1.html">Carbohydrates </a></li><li><a href="../19305/vitamins--1.html">Vitamins </a></li><li><a href="../19313/biochemistry-the-environment--1.html">Biochemistry & the environment </a></li><li><a href="../19336/proteins-enzymes-ahl--1.html">Proteins & enzymes (AHL) </a></li><li><a href="../19347/nucleic-acids--1.html">Nucleic acids </a></li><li><a href="../19361/biological-pigments--1.html">Biological pigments </a></li><li><a href="../19366/stereochemistry-in-biomolecules-1.html">Stereochemistry in biomolecules</a></li></ul></li><li><a href="../19390/option-c--1.html" class="father">Option C </a><ul class="level-2"><li><a href="../19391/energy-sources-1.html">Energy sources</a></li><li><a href="../19407/fossil-fuels-1.html">Fossil fuels</a></li><li><a href="../19411/nuclear-fusion-nuclear-fission-reactions-1.html">Nuclear fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL) </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li class="selected"><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li class="selected"><a href="environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">'Scaffolding' the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier's principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li><a href="../18598/reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../18852/data-logging--1.html">Data logging </a></li><li><a href="../18853/software-for-graph-plotting--1.html">Software for graph plotting </a></li><li><a href="../18854/spreadsheets-for-data-processing--1.html">Spreadsheets for data processing </a></li><li><a href="../18855/databases-1.html">Databases</a></li><li><a href="../18856/computer-modelling-simulations--1.html">Computer modelling & simulations </a></li></ul></li><li><a href="../16594/group-4-project-1.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../16595/practicalities-1.html">Practicalities</a></li><li><a href="../16596/reflective-statement--2.html">Reflective statement </a></li></ul></li><li><a href="../16666/a-new-laboratory-1.html">A new laboratory?</a></li></ul></li><li><a href="../16284/exams-1.html">Exams</a><ul class="level-1"><li><a href="../16286/essential-facts-1.html" class="father">Essential Facts</a><ul class="level-2"><li><a href="../16287/objectives-command-terms-1.html">Objectives & command terms</a></li><li><a href="../16288/grade-descriptors-1.html">Grade descriptors</a></li><li><a href="../16289/grade-boundaries-1.html">Grade boundaries</a></li></ul></li><li><a href="../16302/paper-1-multiple-choice-1.html" class="father">Paper 1 (Multiple Choice)</a><ul class="level-2"><li><a href="../16303/advice-to-students-paper-1-1.html">Advice to students (Paper 1)</a></li><li><a href="../31515/practice-paper-1-exams-1.html">Practice Paper 1 exams</a></li></ul></li><li><a href="../16305/paper-2-1.html" class="father">Paper 2</a><ul class="level-2"><li><a href="../16306/advice-to-students-paper-2-1.html">Advice to students (Paper 2)</a></li><li><a href="../16307/areas-of-difficulty-1.html">Areas of difficulty</a></li></ul></li><li><a href="../16313/paper-3--1.html" class="father">Paper 3 </a><ul class="level-2"><li><a 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href="../16323/retaking-the-exam-1.html">Retaking the exam</a></li></ul></li><li><a href="../16325/faqs-1.html">FAQs</a></li></ul></li><li><a href="../3147/ib-core-1.html">IB Core</a><ul class="level-1"><li><a href="../3149/learner-profile-1.html">Learner Profile</a></li><li><a href="../21735/extended-essays--1.html" class="father">Extended Essays </a><ul class="level-2"><li><a href="../21736/overview--1.html">Overview </a></li><li><a href="../21780/responsibilities-1.html">Responsibilities</a></li><li><a href="../21790/resources-1.html">Resources</a></li><li><a href="../21800/research-1.html">Research</a></li><li><a href="../21804/writing-the-essay-1.html">Writing the essay</a></li><li><a href="../21810/assessment-1.html">Assessment</a></li><li><a href="../22434/summary-of-advice--1.html">Summary of advice </a></li><li><a href="../25272/faqs--1.html">FAQs </a></li></ul></li><li><a href="../307/theory-of-knowledge-tok-1.html" class="father">Theory of Knowledge (TOK)</a><ul class="level-2"><li><a href="../41171/the-12-tok-concepts-1.html">The 12 TOK concepts</a></li><li><a href="../3507/why-tok-chemistry-1.html">Why TOK & Chemistry?</a></li><li><a href="../3505/a-modern-paradigm-1.html">A modern paradigm</a></li></ul></li></ul></li><li><a href="../17783/fast-track-to-tests-questions-1.html">Fast track to tests & questions</a><ul class="level-1"><li><a href="../17784/sl-multiple-choice-tests-on-individual-topics-1.html">SL Multiple choice tests on individual topics</a></li><li><a href="../24351/sl-multiple-choice-quizzes-on-sub-topics-1.html">SL Multiple choice 'quizzes' on sub-topics</a></li><li><a href="../31519/sl-practice-paper-1-exams-1.html">SL Practice Paper 1 exams</a></li><li><a href="../17786/sl-questions-on-each-sub-topic-1.html">SL Questions on each sub-topic</a></li><li><a href="../20431/sl-paper-3-section-a-questions-1.html">SL Paper 3 Section A questions</a></li><li><a href="../17792/sl-questions-on-the-options-1.html">SL Questions on the options</a></li><li><a href="../24897/sl-quizzes-on-option-sub-topics--1.html">SL Quizzes on option sub-topics </a></li><li><a href="../17785/hl-multiple-choice-tests-on-individual-topics-1.html">HL Multiple choice tests on individual topics</a></li><li><a href="../24352/hl-multiple-choice-quizzes-on-sub-topics-1.html">HL Multiple choice 'quizzes' on sub-topics</a></li><li><a href="../31520/hl-practice-paper-1-exams--1.html">HL Practice Paper 1 exams </a></li><li><a href="../17787/hl-questions-on-each-sub-topic--1.html">HL Questions on each sub-topic </a></li><li><a href="../20428/hl-paper-3-section-a-questions-1.html">HL Paper 3 Section A questions</a></li><li><a href="../17793/hl-questions-on-the-options-1.html">HL Questions on the options</a></li><li><a href="../24973/hl-quizzes-on-option-sub-topics-1.html">HL Quizzes on option sub-topics</a></li><li><a href="../41573/printable-versions-of-written-tasks--1.html">Printable versions of written tasks </a></li></ul></li><li><a 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biomolecules</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25034/mc-test-stereochemistry-in-biomolecules--1.html" title="MC test: Stereochemistry in biomolecules ">MC test: Stereochemistry in biomolecules </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19373/stereochemistry-in-biomolecules-questions-1.html" title="Stereochemistry in biomolecules questions">Stereochemistry in biomolecules questions</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../24871/stereochemistry-in-biomolecules-answers--1.html" title="Stereochemistry in biomolecules answers ">Stereochemistry in biomolecules answers </a></li></ul></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../19390/option-c--1.html" title="Option C ">Option C </a></li><ul class="level-1 "><li class=" 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global warming</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19450/environmental-impact-global-warming-questions--1.html" title="Environmental impact - global warming questions ">Environmental impact - global warming questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25190/environmental-impact-global-warming-answers-1.html" title="Environmental impact - global warming answers">Environmental impact - global warming answers</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html" title="Electrochemistry, rechargeable batteries & fuel cells">Electrochemistry, rechargeable batteries & fuel cells</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a 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title="Nuclear fusion & fission (HL) ">Nuclear fusion & fission (HL) </a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25269/mc-test-nuclear-fusion-nuclear-fission-hl-1.html" title="MC test: Nuclear fusion & nuclear fission (HL)">MC test: Nuclear fusion & nuclear fission (HL)</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19468/nuclear-fusion-fission-reactions-hl-questions--1.html" title="Nuclear fusion & fission reactions (HL) questions ">Nuclear fusion & fission reactions (HL) questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25205/nuclear-fusion-fission-reactions-hl-answers-1.html" title="Nuclear fusion & fission reactions (HL) answers">Nuclear fusion & fission reactions (HL) answers</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19470/photovoltaic-cells-and-dsscs-1.html" title="Photovoltaic cells and DSSCs">Photovoltaic cells and DSSCs</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25302/mc-test-photovoltaic-cells-dsscs-1.html" title="MC test: Photovoltaic cells & DSSCs">MC test: Photovoltaic cells & DSSCs</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19471/photovoltaic-cells-and-dsscs-questions--1.html" title="Photovoltaic cells and DSSCs questions ">Photovoltaic cells and DSSCs questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25206/photovoltaic-cells-and-dsscs-answers-1.html" title="Photovoltaic cells and DSSCs answers">Photovoltaic cells and DSSCs answers</a></li></ul></ul><li class="ancestor parent" style="padding-left: 0px"><i class="expander fa fa-caret-right fa-rotate-90"></i><a href="../19078/option-d-1.html" title="Option D">Option D</a></li><ul class="level-1 expanded"><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19079/pharmaceutical-products-drug-action--1.html" title="Pharmaceutical products & drug action ">Pharmaceutical products & drug action </a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25440/mc-test-pharmaceutical-products-drug-action-1.html" title="MC test: Pharmaceutical products & drug action">MC test: Pharmaceutical products & drug action</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19154/pharmaceutical-products-drug-action-questions--1.html" title="Pharmaceutical products & drug action questions ">Pharmaceutical products & drug action questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25270/pharmaceutical-products-drug-action-answers--1.html" title="Pharmaceutical products & drug action answers ">Pharmaceutical products & drug action answers </a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19158/aspirin-penicillin--1.html" title="Aspirin & penicillin ">Aspirin & penicillin </a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25684/mc-test-aspirin-penicillin-1.html" title="MC test: Aspirin & penicillin">MC test: Aspirin & penicillin</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19171/aspirin-penicillin-questions-1.html" title="Aspirin & penicillin questions">Aspirin & penicillin questions</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25313/aspirin-penicillin-answers--1.html" title="Aspirin & penicillin answers ">Aspirin & penicillin answers </a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19174/opiates-1.html" title="Opiates">Opiates</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25494/mc-test-opiates-1.html" title="MC test: Opiates">MC test: Opiates</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19176/opiates-questions-1.html" title="Opiates questions">Opiates questions</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25356/opiates-answers--1.html" title="Opiates answers ">Opiates answers </a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19184/ph-regulation-of-the-stomach-1.html" title="pH regulation of the stomach">pH regulation of the stomach</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25683/mc-test-ph-regulation-of-the-stomach-1.html" title="MC test: pH regulation of the stomach">MC test: pH regulation of the stomach</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19185/ph-regulation-of-the-stomach-questions--1.html" title="pH regulation of the stomach questions ">pH regulation of the stomach questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25391/ph-regulation-of-the-stomach-answers-1.html" title="pH regulation of the stomach answers">pH regulation of the stomach answers</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19194/antiviral-medications--1.html" title="Antiviral medications ">Antiviral medications </a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander 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class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25687/mc-test-taxol-a-chiral-auxiliary-case-study-1.html" title="MC test: Taxol - a chiral auxiliary case study">MC test: Taxol - a chiral auxiliary case study</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19256/taxol-questions--1.html" title="Taxol questions ">Taxol questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25638/taxol-answers-1.html" title="Taxol answers">Taxol answers</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19258/nuclear-medicine--1.html" title="Nuclear medicine ">Nuclear medicine </a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../26020/mc-test-nuclear-medicine-1.html" title="MC test: Nuclear 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</div><section id="main-content"><div id="toc-1672969710" class="toc"><a href="#" class="toc-switcher" title="Show table of contents"><small><i class="fa fa-reorder"></i> Table of contents <span class="pull-right"><i class="fa fa-chevron-down"></i></span></small></a></div><h1><img class="ico" src="../../../img/icons/standard-1.png"> <img class="ico" src="../../../img/icons/higher-1.png"> D.6 Environmental impact of some medications (2 hours)</h1><div class="pinkBg"><div><h2>Pause for thought</h2><p><strong>Supercritical carbon dioxide</strong></p><p>Solvents are traditionally volatile organic substances which are toxic to all living organisms. They affect the nervous and respiratory systems and many, particularly chlorinated solvents such as dichloromethane, affect the liver and kidneys. Many also contribute to photochemical smog by forming secondary pollutants and also some are greenhouse gases and/or contribute towards ozone depletion. Some may also pollute ground water. The pharmaceutical industry requires large quantities of solvents to produce drugs on an industrial scale and much of the solvents used ends up as waste.</p><p>Companies are more and more switching to using supercritical carbon dioxide in place of traditional organic solvents. Supercritical carbon dioxide is now used in the extraction of caffeine and essential oils from plant materials, and to extract the required product(s) during the multi-stage synthesis of drugs. This has many advantages. Supercritical carbon dioxide is much greener and safer to the environment than traditional solvents such as propanone or dichloromethane. The extractions can also occur at much lower temperatures than, for example, using steam distillation, which means that the desired products are less likely to be thermally decomposed or denatured during the extractions. Supercritical carbon dioxide is also very easy to remove. It is true that, when released into the atmosphere, carbon dioxide is a greenhouse gas, but it is not adding to the total amount of greenhouse gases if the source of the supercritical carbon dioxide was the atmosphere in the first place.</p><p>So what is supercritical carbon dioxide? Chemistry teachers are familiar with carbon dioxide gas and solid carbon dioxide, “dry ice”, but most will not have come across ‘liquid’ carbon dioxide. The critical point of carbon dioxide (not to be confused with the triple point, when all three phases exist in equilibrium) is at 304.25 K and 7.39 x 10<sup>6</sup> Pa. Above its critical point it behaves as a supercritical fluid, which expands to fill its container as if it were a gas but with a density as if it were a liquid.</p><hr class="hidden"><p style="text-align: center;"><img alt="" class="noborder" src="../../../ib/chemistry/images/2014-Options/Option-D/Carbon-dioxide-phase-diagram.jpg" style="width: 489px; height: 480px;" title="Image from Wikimedia Creative Commons"></p><p style="text-align: center;">Phase diagram for carbon dioxide (Image from Wikimedia Creative Commons)</p><hr class="hidden"></div></div><hr class="hidden"><div class="box"><h2>Nature of Science</h2><p>The design, production and distribution of medications involve considerable ethical implications and risks which need to be considered by the whole community as well as by the scientific community. Both the side effects of medications on the patient and the side effects of the development, production and use of medications on the environment (i.e. disposal of nuclear waste, solvents and antibiotic waste) need to be taken into account.</p><hr class="hidden"></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h3><b><span style="font-weight: normal; "></span></b></h3><div class="yellowBg"><div><h2><b><span style="font-weight: normal; "><strong>Learning outcomes</strong></span></b></h2><p>After studying this topic students should be able to:</p><p><strong>Understand:</strong></p><ul><li>High-level waste (HLW) is radioactive waste that emits large amounts of ionizing radiation for a long period of time.</li><li>Low-level waste (LLW) is radioactive waste that emits small amounts of ionizing radiation for a short period of time.</li><li>Resistance to antibiotics occurs when micro-organisms become resistant to antibacterials.</li></ul><hr class="hidden"><p><strong>Apply their knowledge to:</strong></p><ul><li>Describe the environmental impact of the disposal of radioactive medical waste.</li><li>Discuss the environmental issues related to left-over solvents.</li><li>Explain the dangers associated with antibiotic waste, from the improper disposal of drugs and animal waste, and the development of antibiotic resistance.</li><li>Discuss the basics of green chemistry (sustainable chemistry) processes.</li><li>Explain how green chemistry was used to develop the precursor for oseltamivir (Tamiflu).</li></ul></div></div></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal;"></span></b></h4><div class="yellowBg"><div><h4><b><span style="font-weight: normal;"><strong>Clarification notes</strong></span></b></h4><p><span style="font-weight: normal;">The structure of </span>oseltamivir can be found in Section 37 of the data booklet.</p><hr class="hidden"><h4>International-mindedness</h4><p>Pharmaceutical companies are multi-national companies. How do they determine how to spend their funds on research to develop new medications? For example, do they have a responsibility to research medications for rare diseases, even though it is unlikely to provide them with significant financial profit?<br>The production of a drug typically involves a number of different organic reactions. Consider the ethics governing the synthesis of new drugs. Are the standards and practices relating to the design and mIB Docs (2) Teamfacture of pharmaceutical products the same worldwide, or do they vary by country and region?</p></div></div></td></tr></tbody></table></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h2><span style=""><b><span style="font-weight: normal;"><strong>Teaching tips</strong></span></b></span></h2><p><span style=""><span style="font-weight: normal;">This is an important topic but </span></span>not easy to teach as much of it is factual, some of it is extremely complicated (e.g. the synthesis of shikimic acid, the precursor for Tamiflu) and whilst it can provoke much discussion it does not readily lend itself to one or two mark short-answer questions.</p><p>The use of radioactive isotopes in medicine is covered in the AHL material so students will not be expected to know about specific isotopes but they should have some understanding of the importance of half-life as this is one of the factors that distinguish between low-level nuclear waste and high-level nuclear waste. I think they also need to be aware of the different types of radiation emitted and I do cover what happens to the radioactive element when it emits alpha or beta radiation even though balancing nuclear equations is not supposed to be covered until D.8. The video given as the first item in 'Other resources' below is well worth showing to cover this part of the sub-topic.</p><p>Explain that waste volatile solvents can cause considerable harm to humans and other animals both as primary pollutants but also they can react to form secondary pollutants (e.g. peroxyacylnitrates, PAN) in the atmosphere.</p><p>You may well have already covered the importance of not overprescribing and the use and disposal of antibiotics in animals in <a href="../19158/aspirin-penicillin--1.html" title="New 2014 programme (First exams 2016) » Options » Option D » Aspirin & penicillin ">D.2</a>.</p><p>Green chemistry encourages the reduction and prevention of pollution at source. It does this by trying to minimise the use and formation of substances harmful to the environment. Explain the concept of atom economy and stress its importance to green chemistry.</p><p>The different ways of synthesising oseltamivir (Tamiflu) are far too complex for IB students, so stress that each new way tries to provide a more sustainable route. The normal precursor is shikimic acid which can be obtained <a href="http://pubs.acs.org/doi/abs/10.1021/ed082p599">in low yield (2-7%) </a>from a plant (the Chinese star anise plant). This is inefficient and environmentally unfriendly and cannot produce enough for industrial production. Synthesis of shikimic acid in the laboratory is a multi-step process with a very low atom economy. It can now be obtained in a much greener way through bioengineering using bacteria.</p><hr class="hidden"></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal; "><strong>Study guide</strong></span></b></h4><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><a href="http://ukcatalogue.oup.com/product/education/international/ibdiploma/studyguides/9780199151424.do?"><b><span style="font-weight: normal;"><img alt="" class="left noborder" src="../../../ib/chemistry/images/2014%20Basic%20information/New%20cover.jpg" style="width: 67px; height: 96px;"></span></b></a></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><hr class="hidden"><p><b><span style="font-weight: normal;">Page 1</span></b><span style="font-weight: normal;">61</span><b><span style="font-weight: normal;"> </span></b></p><hr class="hidden"><h2>Questions</h2><p>For ten 'quiz' questions (for quick testing of knowledge and understanding with the answers explained) see <a href="../25686/mc-test-environmental-impact-of-some-medications-1.html" title="Options » Option D » Environmental impact of some medications » MC test: Environmental impact of some medications">MC test: Environmental impact of some medications</a> .</p><p>For short-answer questions see <a href="../19216/environmental-impact-of-some-medications-questions-1.html" title="Options » Option D » Environmental impact of some medications » Environmental impact of some medications questions">Environmental impact of some medications questions</a> together with the worked answers on a separate page <a href="../25628/environmental-impact-of-some-medications-answers-1.html" title="Options » Option D » Environmental impact of some medications » Environmental impact of some medications answers">Environmental impact of some medications answers</a>.</p><hr class="hidden"><h4><span style=""><b><span style="font-weight: normal;"><strong>Vocabulary list</strong></span></b></span></h4><p><span style=""><span style="font-weight: normal;">low-level nuclear waste, LLW<br>high-level nuclear waste, HLW<br>green chemistry<br>atom economy<br>precursor</span></span></p><hr class="hidden"><hr class="hidden"><h4></h4></td></tr></tbody></table></div><hr class="hidden"><div class="greenBg"><div><h2 id="header-12">Teaching slides</h2><p>Teachers may wish to share these slides with students for learning or for reviewing key concepts.</p><div id="myCarousel-13" class="carousel slide" data-id="584"><!-- Carousel items --><div class="carousel-inner"><div class="active item"><a class="fancy" href="../../../tib-galleries/3-584/ei1.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei1.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei2.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei2.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei3.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei3.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei4.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei4.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei5.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei5.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei6.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei6.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei7.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei7.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei8.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei8.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei9.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei9.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/ei10.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/ei10.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-584/d611.png" rel="gallery-584" title=""><img alt="" src="files/tib-galleries/3-584/d611.png"></a><div class="carousel-caption"><p>Environmental impact of some medications: </p></div></div></div><!-- Carousel nav --><a class="carousel-control left" href="#myCarousel-13" data-slide="prev">‹</a><a class="carousel-control right" href="#myCarousel-13" data-slide="next">›</a><div class="tib-indicators"><img class="" title="Click to view" style="margin: 10px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei1-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei2-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei3-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei4-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei5-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei6-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei7-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei8-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei9-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/ei10-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-584/d611-thumb128.jpg"></div></div><p> </p></div></div><hr class="hidden"><div class="blueBg"><h2><span style="font-weight: bold;">Other resources</span></h2><p><strong>1. </strong>An excellent video from the International Atomic Energy Agency (IAEI), which looks at the methods of disposal of radioactive waste (both low-level and high-level) worldwide.</p><p style="text-align: center"><iframe allowfullscreen="" frameborder="0" height="280" src="https://www.youtube.com/embed/3QXSkXHDZgU" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/3QXSkXHDZgU" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-1" name="video-1"> </span> Dealing with radioactive waste</a></p><hr class="hidden"><p><strong>2.</strong> A video from World Business Review on the management of waste solvent which looks at how solvents are cleaned and recycled in industry.</p><p style="text-align: center"><iframe allowfullscreen="" frameborder="0" height="280" src="https://www.youtube.com/embed/RIIL4WufF_o" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/RIIL4WufF_o" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-2" name="video-2"> </span> Managing waste solvents</a></p><hr class="hidden"><p><strong>3.</strong> A general introduction to green chemistry by Martyn Poliakoff as part of the Nottinghamscience series.</p><p style="text-align: center"><iframe allowfullscreen="" frameborder="0" height="280" src="https://www.youtube.com/embed/_KYiLFkMQ_E" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/_KYiLFkMQ_E" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-3" name="video-3"> </span> Green chemistry</a></p><hr class="hidden"><p><strong>4. </strong>For those with a real interest, the following article summarises some of the different ways in which oseltamivir has been synthesised: <a href="http://newdrugapprovals.org/2013/07/20/recent-progress-in-the-synthesis-of-tamiflu/">Recent progress in the synthesis of Tamiflu</a></p><hr class="hidden"></div></section></article><section id="media-extras"><div class="page-actions no-print navbar inline hidden-desktop"><div class="navbar-inner"><ul class="nav"><li><a class="presentation" href="#" onclick="return false;"><i class="fa fa-desktop"></i></a></li><li><a class="print-section-blog" href="#" onclick="return false;"><i class="fa fa-print"></i></a></li><li><a class="page-bookmarker" data-ticket="IB Docs (2) Team" data-pid="19211" href="#" onclick="return false;"><i class="fa fa-star"></i></a></li><li><a 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