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	<title>DP Chemistry: Electrochemistry, rechargeable batteries & fuel cells</title>
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href="../19290/introduction-to-biochemistry--1.html">Introduction to biochemistry  </a></li><li><a href="../19287/proteins-enzymes--1.html">Proteins & enzymes </a></li><li><a href="../19291/lipids-1.html">Lipids</a></li><li><a href="../19299/carbohydrates--1.html">Carbohydrates </a></li><li><a href="../19305/vitamins--1.html">Vitamins   </a></li><li><a href="../19313/biochemistry-the-environment--1.html">Biochemistry & the environment </a></li><li><a href="../19336/proteins-enzymes-ahl--1.html">Proteins & enzymes (AHL)   </a></li><li><a href="../19347/nucleic-acids--1.html">Nucleic acids   </a></li><li><a href="../19361/biological-pigments--1.html">Biological pigments   </a></li><li><a href="../19366/stereochemistry-in-biomolecules-1.html">Stereochemistry in biomolecules</a></li></ul></li><li class="selected"><a href="../19390/option-c--1.html" class="father">Option C </a><ul class="level-2"><li><a href="../19391/energy-sources-1.html">Energy sources</a></li><li><a href="../19407/fossil-fuels-1.html">Fossil fuels</a></li><li><a href="../19411/nuclear-fusion-nuclear-fission-reactions-1.html">Nuclear fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li class="selected"><a href="electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL)    </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin  </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li><a href="../19211/environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine  </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">&#039;Scaffolding&#039; the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier&#039;s principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li><a href="../18598/reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../18852/data-logging--1.html">Data logging </a></li><li><a href="../18853/software-for-graph-plotting--1.html">Software for graph plotting </a></li><li><a href="../18854/spreadsheets-for-data-processing--1.html">Spreadsheets for data processing </a></li><li><a href="../18855/databases-1.html">Databases</a></li><li><a href="../18856/computer-modelling-simulations--1.html">Computer modelling & simulations </a></li></ul></li><li><a href="../16594/group-4-project-1.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../16595/practicalities-1.html">Practicalities</a></li><li><a href="../16596/reflective-statement--2.html">Reflective statement </a></li></ul></li><li><a href="../16666/a-new-laboratory-1.html">A new laboratory?</a></li></ul></li><li><a href="../16284/exams-1.html">Exams</a><ul class="level-1"><li><a href="../16286/essential-facts-1.html" class="father">Essential Facts</a><ul class="level-2"><li><a href="../16287/objectives-command-terms-1.html">Objectives & command terms</a></li><li><a href="../16288/grade-descriptors-1.html">Grade descriptors</a></li><li><a href="../16289/grade-boundaries-1.html">Grade boundaries</a></li></ul></li><li><a href="../16302/paper-1-multiple-choice-1.html" class="father">Paper 1 (Multiple Choice)</a><ul class="level-2"><li><a href="../16303/advice-to-students-paper-1-1.html">Advice to students (Paper 1)</a></li><li><a href="../31515/practice-paper-1-exams-1.html">Practice Paper 1 exams</a></li></ul></li><li><a href="../16305/paper-2-1.html" class="father">Paper 2</a><ul class="level-2"><li><a href="../16306/advice-to-students-paper-2-1.html">Advice to students (Paper 2)</a></li><li><a href="../16307/areas-of-difficulty-1.html">Areas of difficulty</a></li></ul></li><li><a href="../16313/paper-3--1.html" class="father">Paper 3 </a><ul class="level-2"><li><a href="../16314/advice-to-students-paper-3-1.html">Advice to students (Paper 3)</a></li><li><a href="../16342/data-response-questions-1.html">Data response questions</a></li><li><a href="../20054/experimental-work-questions-1.html">Experimental work questions</a></li></ul></li><li><a href="../16324/the-examination-process-1.html" class="father">The examination process</a><ul class="level-2"><li><a href="../16316/setting-the-exam-papers-1.html">Setting the exam papers</a></li><li><a href="../16317/predicted-grades-1.html">Predicted grades</a></li><li><a href="../16318/marking-the-papers-1.html">Marking the papers</a></li><li><a href="../16319/commenting-on-the-exams-1.html">Commenting on the exams</a></li><li><a href="../16320/grade-awarding-1.html">Grade Awarding</a></li><li><a href="../16321/enquiry-upon-results-1.html">Enquiry upon results</a></li><li><a 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Section A questions</a></li><li><a href="../17792/sl-questions-on-the-options-1.html">SL Questions on the options</a></li><li><a href="../24897/sl-quizzes-on-option-sub-topics--1.html">SL Quizzes on option sub-topics </a></li><li><a href="../17785/hl-multiple-choice-tests-on-individual-topics-1.html">HL Multiple choice tests on individual topics</a></li><li><a href="../24352/hl-multiple-choice-quizzes-on-sub-topics-1.html">HL Multiple choice &#039;quizzes&#039; on sub-topics</a></li><li><a href="../31520/hl-practice-paper-1-exams--1.html">HL Practice Paper 1 exams </a></li><li><a href="../17787/hl-questions-on-each-sub-topic--1.html">HL Questions on each sub-topic </a></li><li><a href="../20428/hl-paper-3-section-a-questions-1.html">HL Paper 3 Section A questions</a></li><li><a href="../17793/hl-questions-on-the-options-1.html">HL Questions on the options</a></li><li><a href="../24973/hl-quizzes-on-option-sub-topics-1.html">HL Quizzes on option sub-topics</a></li><li><a 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28px"><i class="expander fa fa-caret-right "></i><a href="../25207/mc-test-solar-energy-1.html" title="MC test: Solar energy">MC test: Solar energy</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19430/solar-energy-questions-1.html" title="Solar energy questions">Solar energy questions</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25189/solar-energy-answers-1.html" title="Solar energy answers">Solar energy answers</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19437/environmental-impact-global-warming-1.html" title="Environmental impact - global warming">Environmental impact - global warming</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25236/mc-test-environmental-impact-global-warming-1.html" title="MC test: Environmental impact – 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style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19470/photovoltaic-cells-and-dsscs-1.html" title="Photovoltaic cells and DSSCs">Photovoltaic cells and DSSCs</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25302/mc-test-photovoltaic-cells-dsscs-1.html" title="MC test: Photovoltaic cells & DSSCs">MC test: Photovoltaic cells & DSSCs</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19471/photovoltaic-cells-and-dsscs-questions--1.html" title="Photovoltaic cells and DSSCs questions  ">Photovoltaic cells and DSSCs questions  </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25206/photovoltaic-cells-and-dsscs-answers-1.html" title="Photovoltaic cells and DSSCs answers">Photovoltaic cells and DSSCs answers</a></li></ul></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../19078/option-d-1.html" title="Option D">Option D</a></li><ul class="level-1 "><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19079/pharmaceutical-products-drug-action--1.html" title="Pharmaceutical products & drug action ">Pharmaceutical products & drug action </a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25440/mc-test-pharmaceutical-products-drug-action-1.html" title="MC test: Pharmaceutical products & drug action">MC test: Pharmaceutical products & drug action</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19154/pharmaceutical-products-drug-action-questions--1.html" title="Pharmaceutical products & drug action questions ">Pharmaceutical products & drug action questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa 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title="Aspirin & penicillin answers ">Aspirin & penicillin answers </a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19174/opiates-1.html" title="Opiates">Opiates</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25494/mc-test-opiates-1.html" title="MC test: Opiates">MC test: Opiates</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19176/opiates-questions-1.html" title="Opiates questions">Opiates questions</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25356/opiates-answers--1.html" title="Opiates answers ">Opiates answers </a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19184/ph-regulation-of-the-stomach-1.html" title="pH regulation of the stomach">pH regulation of the stomach</a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25683/mc-test-ph-regulation-of-the-stomach-1.html" title="MC test: pH regulation of the stomach">MC test: pH regulation of the stomach</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19185/ph-regulation-of-the-stomach-questions--1.html" title="pH regulation of the stomach questions ">pH regulation of the stomach questions </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25391/ph-regulation-of-the-stomach-answers-1.html" title="pH regulation of the stomach answers">pH regulation of the stomach answers</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19194/antiviral-medications--1.html" title="Antiviral medications ">Antiviral medications </a></li><ul class="level-2 "><li class="" 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class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25687/mc-test-taxol-a-chiral-auxiliary-case-study-1.html" title="MC test: Taxol - a chiral auxiliary case study">MC test: Taxol - a chiral auxiliary case study</a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19256/taxol-questions--1.html" title="Taxol questions  ">Taxol questions  </a></li><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../25638/taxol-answers-1.html" title="Taxol answers">Taxol answers</a></li></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../19258/nuclear-medicine--1.html" title="Nuclear medicine  ">Nuclear medicine  </a></li><ul class="level-2 "><li class="" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../26020/mc-test-nuclear-medicine-1.html" title="MC test: Nuclear 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</div><section id="main-content"><div id="toc-1672969695" class="toc"><a href="#" class="toc-switcher" title="Show table of contents"><small><i class="fa fa-reorder"></i> Table of contents <span class="pull-right"><i class="fa fa-chevron-down"></i></span></small></a></div><h1><img class="ico" src="../../../img/icons/higher-1.png"> C.6 Electrochemistry, rechargeable batteries &amp; fuel cells<br>(4 hours)</h1><div class="pinkBg"><div><h2>Pause for thought</h2><p>The first crude fuel cells were actually invented as long ago as 1838 by William Grove, a Welshman and independently by Christian Sch&ouml;nbein from Germany.</p><p>It was the <a href="http://www.nasa.gov/topics/technology/hydrogen/fc_shuttle.html">NASA space programme</a> that really developed them to become a viable technology. The space shuttle contains three fuel cells, which operate as independent power sources. These use oxygen and hydrogen gas and an electrolyte of potassium hydroxide. Each one is capable of supplying 12 kW peak and 7 kW maximum continuous power supply which is ample for the average power consumption of the shuttle. As well as providing electrical power and heat, the product, water, is used by the astronauts for drinking.</p><hr class="hidden"><p style="text-align: center;"><img alt="" class="noborder" src="../../../ib/chemistry/images/2014-Options/Option-C/Toyota-Mirai.png" style="width: 320px; height: 152px;" title="Image from Toyota http://www.toyota.com/mirai/fcv.html"></p><p style="text-align: center;">Cut-away of the <a href="http://www.toyota.com/mirai/fcv.html">Toyota Mirai</a> showing the fuel cell stacks beneath the driver and passenger seats and the yellow hydrogen fuel tanks in the rear.</p><hr class="hidden"><p>Only now are fuel cells being seriously used to power cars. This year Toyota plans to build 700 cars running on hydrogen fuel cells. The car, the <a href="http://www.toyota.com/mirai/fcv.html">Toyota Mirai</a>, has a range of 312 miles (502 km) from a full tank. The first cars went on sale in the US in August 2015 at a basic cost (before any government subsidies) of $57 500. The relatively high cost and the current lack of hydrogen fuel stations are two initial hurdles that will need to be overcome. Ultimately vehicles powered by fuel cells (FCVs) may well prove to be the best answer to providing transport for the masses that does not rely on fossil fuels and so significantly reduce the emission of polluting greenhouse gases.</p><hr class="hidden"></div></div><hr class="hidden"><div class="box"><div><h2 id="anchor-2">Nature of science</h2><p>Redox reactions can be used as a good source of electricity but the disposal of batteries can cause environmental problems.</p><hr class="hidden"></div></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><div class="yellowBg"><div><h2 id="anchor-3"><strong><strong>Learning outcomes</strong></strong></h2><p>After studying this topic students should be able to:</p><p><strong><strong>Understand:</strong></strong></p><ul><li>Electrochemical cells have internal resistance because of the finite time it takes for ions to diffuse.</li><li>The internal resistance of a cell limits the current it can produce.</li><li>The voltage of a battery primarily depends on the type of materials used, while the total work output depends on their quantity.</li><li>In primary cells the electrochemical reaction is non-reversible. Rechargeable cells involve redox reactions that can be reversed using electricity.</li><li>Fuel cells convert the chemical energy that is contained in the consumed fuels directly into electrical energy.</li><li>Microbial fuel cells, MFCs, which use different carbohydrates or substrates present in waste waters as the fuel, are a possible sustainable energy source.</li><li>The potential of a half-cell under non-standard conditions can be calculated from the Nernst equation:<br><img alt="" class="noborder" src="../../../ib/chemistry/images/2014-Options/Option-C/Nernst-equation.jpg" style="width: 153px; height: 35px;"></li><li>Concentration cells contain the same electrodes but the concentration of the electrolyte solutions at the cathode and anode are different.</li></ul><hr class="hidden"><p><strong>Apply their knowledge to:</strong></p><ul><li>Distinguish between fuel cells and primary cells.</li><li>Deduce the half equations for the electrode reactions in a fuel cell.</li><li>Compare fuel cells with rechargeable batteries.</li><li>Discuss the advantages of different types of cells in terms of size, mass and voltage.</li><li>Solve problems using the Nernst equation.</li><li>Calculate the thermodynamic efficiency (&Delta;<em>G</em>/&Delta;<em>H</em>) of a fuel cell.</li><li>Explain the workings of rechargeable batteries and fuel cells (including diagrams and relevant half-equations).</li></ul></div></div></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal;"></span></b></h4><div class="yellowBg"><div><h4><b><span style="font-weight: normal;"><strong>Clarification notes</strong></span></b></h4><p>Consider a battery to be a portable electrochemical source comprising of one or more voltaic (galvanic) cells connected in series.</p><p>The Nernst equation is given in Section 1 of the data booklet.</p><p>Consider hydrogen and methanol as fuels for fuel cells and consider the operation of fuel cells under both acid and alkaline conditions. Familiarity with proton-exchange membrane, PEM, fuel cells is expected.</p><p>Use the <em>Geobacter</em> species of bacteria as an example that can be used in some cells to oxidize ethanoate ions, CH<sub>3</sub>COO<sup>&minus;</sup>, under anaerobic conditions.</p><p>Consider the lead&ndash;acid storage battery, the nickel&ndash;cadmium, NiCd or NiCad, battery and the lithium&ndash;ion battery.</p><p>Familiarity with the half-equations at the anode and cathode and the uses of the different cells is expected.</p><hr class="hidden"><h4>International-mindedness</h4><p>The ways in which spent batteries are disposed of and/or recycled vary from country to country.</p></div></div></td></tr></tbody></table></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h2><span style=""><b><span style="font-weight: normal;"><strong>Teaching tips</strong></span></b></span></h2><p>This sub-topic follows on neatly from <a href="../18350/topics-9-19-1.html" title="New 2014 programme (First exams 2016) » Core &amp; AHL » Teaching each topic &amp; sub-topic » Topics 9 &amp; 19">Topics 9 &amp; 19</a> from the core/AHL. Essentially it is the practical application of voltaic cells so does require some memory work as well as a deeper understanding. The key to the sub-topic is either knowing or being able to deduce the equations for the half-reactions taking place in the different types of rechargeable batteries and fuel cells.</p><p>I start by revising how voltaic cells work and how to calculate the electromotive force for the whole cell (EMF or <em>E</em><sup>⦵</sup><sub>total</sub>) from the standard electrode potentials of the two half-cells. Then go into the specific details for the lead-acid, Ni/Cd and Li-ion rechargeable batteries. Students should realise that when batteries recharge the reaction occurring is the reverse of when it discharges.</p><p>Fuel cells are expensive but have considerable potential. Start with the hydrogen fuel cell and stress that the same overall reaction occurs irrespective of whether the electrolyte is acidic or alkaline but that the half-reactions are different. When methanol is used as the fuel carbon dioxide and water are the products of oxidation. However if the oxidation is carried out anaerobically, as in a microbial fuel cell, then carbon dioxide, hydrogen ions and electrons are formed instead. By using a membrane to allow the passage of the hydrogen ions and the external circuit to allow the flow of electrons a microbial fuel cell can be used to provide a sustainable energy source using waste water and bacteria. Explain the thermodynamic efficiency of a fuel cell including why, in the hydrogen fuel cell, &Delta;<em>G</em><sup>⦵</sup> is smaller in quantitative value than &Delta;<em>H</em><sup>⦵</sup> as work needs to be done to overcome the negative entropy change when gaseous hydrogen and oxygen turn into liquid water. One way to ensure they fully understand this is to get them to work out the value for &Delta;<em>S</em><sup>⦵</sup> (see 2(d) in the<a href="../19455/electrochemistry-rechargeable-batteries-fuel-cells-questions-1.html" title="Electrochemistry, rechargeable batteries &amp; fuel cells questions"> questions</a>).</p><p>The syllabus states that the Nernst equation can be used to calculate the potential of a half-cell in an electrochemical cell, under non-standard conditions. This is not strictly true. It can be used to calculate the potential for non-standard concentrations but not when just the temperature is changed as then the expression &ndash; (<em>RT</em> / <em>nF</em>) ln <em>Q</em> = 0. Give your students plenty of practice at working out the EMF for cells with different concentrations including concentration cells (where only the concentration of the ions in the solutions of otherwise identical half-cells changes).</p><hr class="hidden"></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal;"><strong>Study Guide</strong></span></b></h4><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><a href="http://ukcatalogue.oup.com/product/education/international/ibdiploma/studyguides/9780199151424.do?"><b><span style="font-weight: normal;"><img alt="" class="left noborder" src="../../../ib/chemistry/images/2014%20Basic%20information/New%20cover.jpg" style="width: 67px; height: 96px;"></span></b></a></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><hr class="hidden"><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><b><span style="font-weight: normal;">Page </span></b><span style="font-weight: normal;">163</span></p><hr class="hidden"><h2>Questions</h2><p>For ten &#39;quiz&#39; questions (for quick testing of knowledge and understanding with the answers explained) see <a href="../25258/mc-test-electrochemistry-rechargeable-batteries-fuel-cells-1.html" title="Options » Option C » Electrochemistry, rechargeable batteries &amp; fuel cells » MC test: Electrochemistry, rechargeable batteries &amp; fuel cells">MC test: Electrochemistry, rechargeable batteries &amp; fuel cells</a>.</p><p>For short-answer questions see <a href="../19455/electrochemistry-rechargeable-batteries-fuel-cells-questions-1.html" title="Options » Option C » Electrochemistry, rechargeable batteries &amp; fuel cells » Electrochemistry, rechargeable batteries &amp; fuel cells questions">Electrochemistry, rechargeable batteries &amp; fuel cells questions</a>&nbsp; together with the worked answers on a separate page &nbsp; <a href="../25204/electrochemistry-rechargeable-batteries-fuel-cells-answers-1.html" title="Options » Option C » Electrochemistry, rechargeable batteries &amp; fuel cells » Electrochemistry, rechargeable batteries &amp; fuel cells answers">Electrochemistry, rechargeable batteries &amp; fuel cells answer</a>&nbsp;.</p><hr class="hidden"><h4><span style=""><b><span style="font-weight: normal;"><strong>Vocabulary list</strong></span></b></span></h4><p>Nernst equation<br>concentration cell<br>microbial fuel cell, (MFC)<br>proton exchange membrane (PEM) fuel cell<br>Nickel-cadmium (NiCd or NiCad) battery<br>Lead-acid battery<br>Lithium-ion battery</p><hr class="hidden"><h2 id="anchor-10"><strong>Practical work</strong></h2><p><a href="http://www.instructables.com/id/Microbial-Fuel-Cells-A-Way-to-Generate-Clean-Elect/?ALLSTEPS" target="_blank" title="Labs"><img class="ico" src="../../../img/icons/lab-1.png"> Making a microbial fuel cell </a>- this could make a nice project for your own students.</p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p></td></tr></tbody></table></div><hr class="hidden"><div class="greenBg"><div><h2 id="header-11">Teaching slides</h2><p>Teachers may wish to share these slides with students for learning or for reviewing key concepts.</p><div id="myCarousel-12" class="carousel slide" data-id="540"><!-- Carousel items --><div class="carousel-inner"><div class="active item"><a class="fancy" href="../../../tib-galleries/3-540/ec1.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec1.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec2.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec2.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec3.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec3.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="/files/tib-galleries/3-540/screenshot-2022-02-08-at-154721.png" rel="gallery-540" title=""><img alt="" src="/files/tib-galleries/3-540/screenshot-2022-02-08-at-154721.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec5.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec5.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec6.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec6.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec7.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec7.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec8.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec8.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec9.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec9.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec10.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec10.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec11.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec11.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-540/ec12.png" rel="gallery-540" title=""><img alt="" src="files/tib-galleries/3-540/ec12.png"></a><div class="carousel-caption"><p>Electrochemistry, rechargeable batteries & fuel cells: </p></div></div></div><!-- Carousel nav --><a class="carousel-control left" href="#myCarousel-12" data-slide="prev">&lsaquo;</a><a class="carousel-control right" href="#myCarousel-12" data-slide="next">&rsaquo;</a><div class="tib-indicators"><img class="" title="Click to view" style="margin: 10px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec1-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec2-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec3-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="/files/tib-galleries/3-540/screenshot-2022-02-08-at-154721-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec5-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec6-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec7-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec8-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec9-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec10-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec11-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-540/ec12-thumb128.jpg"></div></div><p>&nbsp;&nbsp;</p></div></div><hr class="hidden"><div class="blueBg"><h2><span style="font-weight: bold;">Other resources</span></h2><p><strong>1. </strong>A good description by BASF on how lithium-ion batteries work.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/2PjyJhe7Q1g?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/2PjyJhe7Q1g" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-1" name="video-1">&nbsp;</span> How lithium-ion batteries work</a></p><hr class="hidden"><p><strong>2.</strong> Another good description - this time on how a lead-acid battery works by Bill Hammack from the University of Illinois.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/rhIRD5YVNbs?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/rhIRD5YVNbs" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-2" name="video-2">&nbsp;</span> How lead-acid batteries work</a></p><hr class="hidden"><p style="text-align: center;"><strong>3.</strong> An animated overview of fuel cells by the Naked Science Scrapbook which provides a good introduction to the different types of fuel cells and why they are useful (but does not include the half-equations).</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/Tk_iIzOUjTU?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/Tk_iIzOUjTU" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-3" name="video-3">&nbsp;</span> Fuel cells</a></p><hr class="hidden"><p><strong>4. </strong>This American Chemistry Society video shows how waste water can be used to produce electricity using microbial fuels cells.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/iaZUsASFI6Y?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/iaZUsASFI6Y" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-4" name="video-4">&nbsp;</span> Using microbial fuel cells to generate electricity</a></p><hr class="hidden"><p style="text-align: center;"></p></div><p style="text-align: center; "></p><p style="text-align: center;"></p></section></article><section id="media-extras"><div class="page-actions no-print navbar inline hidden-desktop"><div class="navbar-inner"><ul class="nav"><li><a class="presentation" href="#" onclick="return false;"><i class="fa fa-desktop"></i></a></li><li><a class="print-section-blog" href="#" onclick="return false;"><i class="fa fa-print"></i></a></li><li><a class="page-bookmarker" data-ticket="IB Docs (2) Team" data-pid="19453" href="#" onclick="return false;"><i class="fa fa-star"></i></a></li><li><a class="personal-notes" href="#" onclick="return false;"><i class="fa fa-file-text"></i></a></li><li><a class="" data-toggle="modal" href="#modal-feedback" onclick="return false;"><i class="fa fa-envelope-o"></i></a></li><li class="dropdown"><a class="dropdown-toggle" data-toggle="dropdown" data-target="#" href="#"><i class="fa fa-share-alt"></i></a><ul class="dropdown-menu" role="menu"><li><a class="" target="_blank" title="Share on Twitter" href="https://twitter.com/share?text=%22Electrochemistry%2C+rechargeable+batteries+%26+fuel+cells%22+-+via+%40InThinker+%23chemistry%0A&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F19453%2Felectrochemistry-rechargeable-batteries-fuel-cells"><i class="fa fa-twitter-square"></i><span>Twitter</span></a></li><li><a class="" target="_blank" title="Share on Facebook" href="https://www.facebook.com/sharer.php?u=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F19453%2Felectrochemistry-rechargeable-batteries-fuel-cells&t=Electrochemistry,+rechargeable+batteries+&+fuel+cells"><i class="fa fa-facebook-square"></i><span>Facebook</span></a></li><li><a class="" href="http://www.linkedin.com/shareArticle?mini=true&url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F19453%2Felectrochemistry-rechargeable-batteries-fuel-cells"><i class="fa fa-linkedin-square"></i><span>LinkedIn</span></a></li><li><a class="" href="https://plus.google.com/share?url=https%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F19453%2Felectrochemistry-rechargeable-batteries-fuel-cells"><i class="fa fa-google-plus-square"></i><span>Google +</span></a></li><li><a class="" href="mailto:?subject=Electrochemistry, rechargeable batteries & fuel cells&body=The first crude fuel cells were actually invented as long ago as 1838 by William Grove, a Welshman and independently by Christian Schönbein from Germany.It was the NASA space programme that really developed them to become...%0Ahttps%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F19453%2Felectrochemistry-rechargeable-batteries-fuel-cells"><i class="fa fa-envelope"></i><span>Email</span></a></li></ul></li><li><a class="" href="chemistry/teaching-materials"><i class="fa fa-puzzle-piece colored"></i></a></li></ul></div></div><div style="border-top: solid 1px #eee;border-bottom: solid 1px #eee;padding: 4px 0 4px 0;line-height: 1em;color: #666;font-size: .8em"><small><em>All materials on this website are for the exclusive use of teachers and students at subscribing schools for the period of their subscription. 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